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VaSA

Our technology for demonstration & commercialization:

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VaSA   for Ammonia Recovery from Wastewater and Digestate Treatment

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The Vacuum Stripping and Absorption (VaSA) technology was invented at SUNY College of Environmental Science and Forestry, Syracuse, NY and granted U.S. Patent No. 10,053,369 in 2018. It couples vacuum stripping and acid absorption to strip ammonia out of ammonia-rich wastewater (e.g., anaerobic digestate, landfill leachate, and liquid animal manure) under optimum vacuum and temperature combinations (typically 46 kPa and 65 degree Celsius) and recover the stripped ammonia by vacuum suction into acidic solutions for production of granular ammonium salts, sellable nitrogen fertilizers and reagent-grade chemicals. This unique process can reduce ammonia concentration from x,000 mg/L to less than 100 mg/L in a few hours of hydraulic retention.

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In addition, the vacuum stripping process enhances solids solubilization due to vacuum-assisted low-temperature thermal and mild-alkali treatment at the vacuum-temperature combination and subsequently increases methane production when stripped digestate is returned to the digesters. It improves dewaterability of digester effluent, and upgrades biosolids to Class A by pathogen reduction. It does not introduce stripping gases, neither need porous packing medium, thus eliminating the costly solid/liquid separation process. Compared with biological nitrogen removal, VaSA eliminates greenhouse gas emission.

 

Funded by NSF Partnerships for Innovation Program and NYS CoE in Healthy Water Solutions, onsite demonstration with 125-gallon VaSA prototype succeeded in January-June 2022 at The City of San Luis Obispo's Water Resource Recovery Facility and received the 2022 Award of Excellence in Innovation and Resilience from California Association of Sanitation Agencies. Pilot tests with landfill leachate were successfully carried out at the Regional Landfill at Ava, NY in May-July 2023.

 

The demonstration of 10-gallon VaSA prototype for pretreatment of dairy manure followed by 18-L anaerobic digesters was fulfilled with scraped and flushed dairy manure from Cal Poly Dairy in June-November 2022.

VaSA    Products
             Gen1 prototype                                                      Gen2 prototype
VaSA-ShortBlankDemister.jpg
Laboratory verification of VaSA    benefits to anaerobic digestion
Digesters-Youl.jpg
Verified benefits of VaSA   pretreatment to anaerobic digestion of dairy manure
ManureDigesters7-17-2022-2.jpg

Technology development files:

[1] U.S. Patent 10,053,369. August 2018. Production of Ammonium Sulfate Using a Vacuum Absorption Process.

https://patents.google.com/patent/US20170291825A1/en

[2] ESF technology flier [download]

[3] Badsha M.A.H., Rathnayake P., Lundquist T., Tao W. 2024. Empowering anaerobic digestion of dairy cow manure with pretreatment and post-treatment using vacuum stripping. Renewable Energy, 237, 121714.

[4] Tao W., Badsha M.A.H., Arachchilage P.W., and Mostafa A. 2024. Simultaneous ammonia recovery and treatment of sludge digestate using vacuum stripping and absorption process: Scale-up design and pilot study. Chemical Engineering Journal, 480, 148336.

[5] Han Y., Agyeman F., Green H., and Tao W. 2022. Stable, high-rate anaerobic digestion through vacuum stripping of digestate. Bioresource Technology, 343, 126133.

[6] Tao W., Bayrakdar A., Wang Y., and Agyeman F. 2019. Three-stage treatment for nitrogen and phosphorus recovery from human urine: hydrolysis, precipitation and vacuum stripping. Journal of Environmental Management249, 109435.

[7] Tao W., Ukwuani A.T., and Agyeman F. 2018. Recovery of ammonia in anaerobic digestate using vacuum thermal stripping - acid absorption process: Scale-up considerations. Water Science & Technology, 78, 878-885. Free online

​[8] Ukwuani A., and Tao W. 2016. Developing a vacuum thermal stripping - acid absorption process for ammonia recovery from anaerobic digester effluent. Water Research, 106, 108-115.

[9] Anwar S.W., and Tao W. 2016. Cost benefit assessment of a novel thermal stripping - acid absorption process for ammonia recovery from anaerobically digested dairy manure. Water Practice and Technology, 11, 355-364.

[10]  Tao W., and Ukwuani A.T. 2015. Coupling thermal stripping and acid absorption for ammonia recovery from dairy manure: Ammonia volatilization kinetics and effects of temperature, pH and dissolved solids content. Chemical Engineering Journal, 280: 188-196.​

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